| dc.date.accessioned |
2013-08-14T10:20:28Z |
und |
| dc.date.accessioned |
2017-10-24T12:19:39Z |
|
| dc.date.available |
2013-08-14T10:20:28Z |
und |
| dc.date.available |
2017-10-24T12:19:39Z |
|
| dc.date.issued |
2013-08-14T10:20:28Z |
|
| dc.identifier.uri |
http://radr.hulib.helsinki.fi/handle/10138.1/3050 |
und |
| dc.identifier.uri |
http://hdl.handle.net/10138.1/3050 |
|
| dc.title |
One-Pot Synthesis of 1-Amido-2-cyclohexene Derivatives Catalysed by Ionic Liquids under Solvent-Free Conditions |
en |
| ethesis.discipline |
Organic chemistry |
en |
| ethesis.discipline |
Orgaaninen kemia |
fi |
| ethesis.discipline |
Organisk kemi |
sv |
| ethesis.department.URI |
http://data.hulib.helsinki.fi/id/c2dd677c-da9c-4011-94b0-27b1585ac1cb |
|
| ethesis.department |
Kemiska institutionen |
sv |
| ethesis.department |
Department of Chemistry |
en |
| ethesis.department |
Kemian laitos |
fi |
| ethesis.faculty |
Matematisk-naturvetenskapliga fakulteten |
sv |
| ethesis.faculty |
Matemaattis-luonnontieteellinen tiedekunta |
fi |
| ethesis.faculty |
Faculty of Science |
en |
| ethesis.faculty.URI |
http://data.hulib.helsinki.fi/id/8d59209f-6614-4edd-9744-1ebdaf1d13ca |
|
| ethesis.university.URI |
http://data.hulib.helsinki.fi/id/50ae46d8-7ba9-4821-877c-c994c78b0d97 |
|
| ethesis.university |
Helsingfors universitet |
sv |
| ethesis.university |
University of Helsinki |
en |
| ethesis.university |
Helsingin yliopisto |
fi |
| dct.creator |
Debraise, Nora |
|
| dct.issued |
2013 |
|
| dct.language.ISO639-2 |
eng |
|
| dct.abstract |
Aminodiene-based Diels-Alder reactions constitute attractive solutions for the construction of six-membered carbocyclic subunits of a number of organic compounds, including natural products. Functionalized acylaminodienes are key intermediates in those reactions with their ability to incorporate various heteroatoms to the Diels-Alder adducts. Taking advantage of this, various 1-acylamino-2-cyclohexene derivatives were synthesised with a novel protocol involving an in situ generation of an amidodiene intermediate. A novel one-pot procedure for the multicomponent coupling reactions of amides, aldehydes, and dienophiles using room temperature ionic liquids as reaction media and catalyst under solvent-free conditions was developed. Short reaction times, easy microwave-assisted procedure, solvent-free conditions and good conversion to product are features of this new protocol. |
en |
| dct.language |
en |
|
| ethesis.language.URI |
http://data.hulib.helsinki.fi/id/languages/eng |
|
| ethesis.language |
English |
en |
| ethesis.language |
englanti |
fi |
| ethesis.language |
engelska |
sv |
| ethesis.thesistype |
pro gradu-avhandlingar |
sv |
| ethesis.thesistype |
pro gradu -tutkielmat |
fi |
| ethesis.thesistype |
master's thesis |
en |
| ethesis.thesistype.URI |
http://data.hulib.helsinki.fi/id/thesistypes/mastersthesis |
|
| dct.identifier.urn |
URN:NBN:fi-fe2017112252008 |
|
| dc.type.dcmitype |
Text |
|
