| dc.date.accessioned |
2015-11-11T11:19:29Z |
und |
| dc.date.accessioned |
2017-10-24T12:19:12Z |
|
| dc.date.available |
2015-11-11T11:19:29Z |
und |
| dc.date.available |
2017-10-24T12:19:12Z |
|
| dc.date.issued |
2015-11-11T11:19:29Z |
|
| dc.identifier.uri |
http://radr.hulib.helsinki.fi/handle/10138.1/5143 |
und |
| dc.identifier.uri |
http://hdl.handle.net/10138.1/5143 |
|
| dc.title |
Synthesis and Self Assembly of Quadruple Hydrogen-Bonded Arrays |
en |
| ethesis.discipline |
Organic chemistry |
en |
| ethesis.discipline |
Orgaaninen kemia |
fi |
| ethesis.discipline |
Organisk kemi |
sv |
| ethesis.department.URI |
http://data.hulib.helsinki.fi/id/c2dd677c-da9c-4011-94b0-27b1585ac1cb |
|
| ethesis.department |
Kemiska institutionen |
sv |
| ethesis.department |
Department of Chemistry |
en |
| ethesis.department |
Kemian laitos |
fi |
| ethesis.faculty |
Matematisk-naturvetenskapliga fakulteten |
sv |
| ethesis.faculty |
Matemaattis-luonnontieteellinen tiedekunta |
fi |
| ethesis.faculty |
Faculty of Science |
en |
| ethesis.faculty.URI |
http://data.hulib.helsinki.fi/id/8d59209f-6614-4edd-9744-1ebdaf1d13ca |
|
| ethesis.university.URI |
http://data.hulib.helsinki.fi/id/50ae46d8-7ba9-4821-877c-c994c78b0d97 |
|
| ethesis.university |
Helsingfors universitet |
sv |
| ethesis.university |
University of Helsinki |
en |
| ethesis.university |
Helsingin yliopisto |
fi |
| dct.creator |
Molina-Gutiérrez, Samantha |
|
| dct.issued |
2015 |
|
| dct.language.ISO639-2 |
eng |
|
| dct.abstract |
The strength and directionality of hydrogen bonds have made them very attractive in the engineering of supramolecular units. This has been translated to the design of multiple hydrogen-bond arrays in order to modify and tune the interaction between supramolecular building blocks. In the present work several bifunctionalized compounds equipped with 7-Amino-1H-[1,8]naphthyridin-2-one as DADA binding unit and a variation of linker moieties by including aromatic groups as benzene and naphthalene, heterocycles as 1,2,3-triazoles, and dendron moieties, by means of reactions as Glaser coupling, Sonogashira coupling and 1,3-dipolar cycloaddition, have been synthesized. Compounds with a dendron structure as linker exhibit adequate solubility in non-polar solvents to execute experiments to study their binding nature. 1H-NMR DOSY experiments suggested that the synthesized dendron compounds were present as dimers and trimers in deuterated dichloromethane. |
en |
| dct.language |
en |
|
| ethesis.language.URI |
http://data.hulib.helsinki.fi/id/languages/eng |
|
| ethesis.language |
English |
en |
| ethesis.language |
englanti |
fi |
| ethesis.language |
engelska |
sv |
| ethesis.thesistype |
pro gradu-avhandlingar |
sv |
| ethesis.thesistype |
pro gradu -tutkielmat |
fi |
| ethesis.thesistype |
master's thesis |
en |
| ethesis.thesistype.URI |
http://data.hulib.helsinki.fi/id/thesistypes/mastersthesis |
|
| dct.identifier.urn |
URN:NBN:fi-fe2017112251491 |
|
| dc.type.dcmitype |
Text |
|
