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Serpentinization and carbonation of the komatiitic rocks in the Komati Complex, Barberton greenstone belt, South Africa

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dc.date.accessioned 2016-11-22T06:05:15Z und
dc.date.accessioned 2017-10-24T12:16:04Z
dc.date.available 2016-11-22T06:05:15Z und
dc.date.available 2017-10-24T12:16:04Z
dc.date.issued 2016-11-22T06:05:15Z
dc.identifier.uri http://radr.hulib.helsinki.fi/handle/10138.1/5860 und
dc.identifier.uri http://hdl.handle.net/10138.1/5860
dc.title Serpentinization and carbonation of the komatiitic rocks in the Komati Complex, Barberton greenstone belt, South Africa en
ethesis.discipline Geology en
ethesis.discipline Geologia fi
ethesis.discipline Geologi sv
ethesis.discipline.URI http://data.hulib.helsinki.fi/id/53a1f507-f7e9-4c0d-8cd2-94ebc19a7174
ethesis.department.URI http://data.hulib.helsinki.fi/id/3d45b9d6-7f3a-4008-a01f-6f27f2263ec4
ethesis.department Institutionen för geovetenskaper och geografi sv
ethesis.department Department of Geosciences and Geography en
ethesis.department Geotieteiden ja maantieteen laitos fi
ethesis.faculty Matematisk-naturvetenskapliga fakulteten sv
ethesis.faculty Matemaattis-luonnontieteellinen tiedekunta fi
ethesis.faculty Faculty of Science en
ethesis.faculty.URI http://data.hulib.helsinki.fi/id/8d59209f-6614-4edd-9744-1ebdaf1d13ca
ethesis.university.URI http://data.hulib.helsinki.fi/id/50ae46d8-7ba9-4821-877c-c994c78b0d97
ethesis.university Helsingfors universitet sv
ethesis.university University of Helsinki en
ethesis.university Helsingin yliopisto fi
dct.creator Rintamäki, Annukka
dct.issued 2016
dct.language.ISO639-2 eng
dct.abstract The ultramafic rocks in the Komati Complex, Barbeton greenstone belt, South Africa have been serpentinized thoroughly and carbonated with variable intensities. Conditions of the serpentinization and carbonation of the ultramafic rocks in the Komati Complex were studied using serpentine phase characterization by Raman spectroscopy, calcite hosted fluid inclusion microthermometry and chlorite geothermometry. Three serpentine phases, lizardite, chrysotile, and antigorite occur in four samples studied with Raman spectroscopy. Antigorite dominates the serpentine mineralogy in two of the samples and other two have large amounts of lizardite and antigorite, chrysotile being a minor constituent in three of the four samples. Abundant antigorite indicates serpentine crystallization above a temperature of ~ 320 °C. Fluid inclusion petrography and microthermometric data revealed four fluid inclusion assemblages (FIA), FIA 1 - FIA 4 in an order from earliest to latest entrapment. The FIAs have homogenization temperatures in the ranges of ~170 - 240 °C (FIA 1), 154 - 163 °C (FIA 2), 149 - 180 °C (FIA 3), 112 - 137 °C (FIA 4). Relatively constant NaCl equivalent salinities in the range of 6.4 - 11 wt-% were recorded for the FIAs 1 and 2, similar salinities were indicated for the FIAs 3 and 4. Chlorite geothermometry yielded temperatures in the approximate range of 150 - 250 °C. Chlorite crystallization is texturally indicated to be related to the formation of the calcite that hosts the fluid inclusions. The overlap of chlorite geothermometry temperatures and the homogenization temperatures of the earliest fluid inclusions (FIA 1) indicates fluid inclusion entrapment at pressures lower than 200 - 300 bar and at temperatures equal to or slightly above the recorded homogenization temperatures. These pressure and temperature estimations suggest that carbonation occurred in a seafloor environment at moderate hydrothermal conditions. The properties of carbonate hosted fluid inclusions resemble those of fluid inclusions reported from Archean greenstone belts and interpreted as Archean seawater by previous contributions. Calcite hosted fluid inclusions may, thus, represent entrapped Archean seawater. en
dct.language en
ethesis.language.URI http://data.hulib.helsinki.fi/id/languages/eng
ethesis.language English en
ethesis.language englanti fi
ethesis.language engelska sv
ethesis.thesistype pro gradu-avhandlingar sv
ethesis.thesistype pro gradu -tutkielmat fi
ethesis.thesistype master's thesis en
ethesis.thesistype.URI http://data.hulib.helsinki.fi/id/thesistypes/mastersthesis
dct.identifier.urn URN:NBN:fi-fe2017112251576
dc.type.dcmitype Text

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