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Browsing by master's degree program "Magisterprogrammet i atmosfärsvetenskaper"

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  • Holm, Sebastian (2023)
    The Differential Mobility Particle Sizer (DMPS) is a widely used instrument in the size distribution measurements of sub-micron aerosol particles. The particles are size classified based on their electrical equivalent diameter by a Differential Mobility Analyser (DMA) in the DMPS. Only charged particles can be measured with a DMPS. An aerosol charger is hence required since most ambient particles are neutral. An estimation of the size dependent charge distribution of the aerosol particles is required to reach a representative size distribution of the whole aerosol population from the raw measurement data. The charged fractions of the population are conventionally calculated by applying bipolar charging (i.e., an ion atmosphere including ions of both polarities charges aerosols by diffusion and ion attachment onto the particles) theories. Fixed charger ion properties have been used to derive approximation to these theories. The charger ion properties in ambient “real-world” measurements are, however, not fixed but proven to vary substantially. These variations may lead to significant differences when comparing to the approximations. A new method for aerosol charging that reduces the uncertainties that originate from unknown properties of the charger ions was tested in this thesis. The method consists of the introduction of a known trace compound (hereafter called doping) into the aerosol sample flow upstream of a bipolar charger. The effect of doping on charger ion mobility distribution was successfully tested in laboratory experiments. A possible enhancement of charging efficiencies of nanoparticles was studied. The charger ion doping was also tested in atmospheric measurements, where it showed an effect on charger ion properties.
  • Leino, Joonas (2022)
    Mars-planeetan kaasukehä koostuu enimmäkseen hiilidioksidista, kun taas vesihöyryä on hyvin vähän. Kaasukehän lämpötila vaihtelee noin +10 ja -130 Celsius-asteen välillä ja pintapaine on vain noin sadasosa Maan ilmakehän paineesta. Marsin kaasukehässä on usein paljon hienojakoista pölyä, joka absorboi tehokkaasti auringonsäteilyä ja täten vaikuttaa kaasukehän toimintaan. Marsin pinnan reagoidessa erittäin nopeasti auringonsäteilyn määrän muutoksiin sekä kaasukehässä olevan pölyn vuoksi rajakerroksen mallinnuksessa käytettävissä malleissa säteilyn parametrisaatioiden täytyy olla mahdollisimman hyviä. Helsingin yliopisto ja Ilmatieteen laitos ovat kehittäneet Marsin kaasukehän tutkimukseen tarkoitetun 1-ulotteisen pylväsmallin. Malli on erittäin nopea ja helposti muokattavissa, joten sillä voidaan testata uusia ilmakehäfysiikan lainalaisuuksia ja algoritmeja, joita voidaan mahdollisesti lisätä kolmiulotteisiin Marsin kaasukehän malleihin. Tämä työ tehtiin osana Ilmatieteen laitoksen Marsin tutkimusryhmää ja työssä tutustutaan Marsin kaasukehän rajakerrokseen sekä pylväsmalliin. Lisäksi mallin antamia tuloksia esitellään ja verrataan Curiosity mönkijän (toiselta nimeltään Mars Science Laboratory, MSL) havaintoihin sekä tutkitaan mallin herkkyyttä sen alustusparametreihin. Mallin ennustamia lämpötilan, vesihöyryn tilavuuden sekoitussuhteen ja suhteellisen kosteuden vuorokausisyklejä verrattiin MSL:n havaintoihin eri vuodenaikoina. MSL laskeutui vuonna 2012 lähelle Marsin päiväntasaajaa Gale-kraatterin pohjalle ja se sisältää Ilmatieteen laitoksen suunnittelemat ja rakentamat mittalaitteet paineelle ja suhteelliselle kosteudelle. Mallin ennustamat vuorokausisyklit vastasivat hyvin mönkijän havaintoja ja tuloksista nähtiin myös lämpötilan suuri vuorokausivaihtelu kaasukehän reagoidessa nopeasti auringonsäteilyn muutoksiin. MSL:n paineen mittauksista (yli 3000 Marsin vuorokautta) nähtiin selvästi hiilidioksidin vuodenaikaiskierto etelänavalta pohjoisnavalle ja päinvastoin. Lisäksi vuoden 2018 globaali pölymyrsky näkyi monissa eri mittaustuloksissa. Mallin herkkyyttä tutkittiin muuttamalla neljää eri alustusparametria: pinnan lämpötilaa ja painetta, ilmapylvään vesisisältöä (PWC) sekä pölyn optista paksuutta (tau). Näiden testien perusteella mallin ennustamiin vuorokauden lämpötilaprofiileihin eniten vaikuttivat pinnan lämpötilan ja pölyn optisen paksuuden alustus, kun taas kosteusprofiileihin eniten vaikuttivat PWC:n ja pölyn optisen paksuuden alustus. Näistä parametreista pinnan paineen alustuksella oli vähiten vaikutusta mallin ennustamiin profiileihin.
  • Hyvärinen, Sara (2023)
    The mean temperature of Earth has been rising due to human-influenced climate change. Climate change has been mostly caused by the rise of greenhouse gases from anthropogenic sources. After carbon dioxide (CO2), the second most important anthropogenic greenhouse gas to climate change is methane (CH4). Approximately half of the methane emissions come from natural sources, including wetlands. The northern high latitude wetlands store large amounts of carbon in permafrost, and the thawing of permafrost could release more methane into the atmosphere. However, there is still much uncertainty related to the methane emissions from the northern high latitude wetlands. The emissions on these wetlands have an annual cycle related to the freezing and thawing of the soil with the highest emissions during summer and the lowest during winter. Climate change can affect the duration and timing of the freezing and thawing periods leaving the winter period shorter. In this thesis, the melting season for the northern high latitude wetlands was defined for four regions: non-permafrost, sporadic, discontinuous and continuous permafrost as well as two smaller regions: Hudson Bay lowlands and Western Siberian lowlands for the years 2011-2020. The melting period was defined with a new method of using the SMOS F/T soil thawing data, which has not been done before this study. The data includes daily information on the freezing state of the soil in the northern latitudes. The melting period methane emissions were defined from the inversion model Carbon Tracker Europe -CH4. The relationship between the emissions, melting period length and mean temperature was studied. Emissions during the spring melting season were detected in all the permafrost regions defined in this study. The fluxes grew stronger as spring progressed and the soil and snow melted. The melting period methane emissions were relatively small compared to the annual emissions (a few per cent of the annual budget). However, the emissions were a little larger than autumn emissions. To understand the melting season emissions better, different drivers in addition to air temperature, like the melting of the permafrost, should be studied in relation to the CH4 emissions.
  • Ala-Könni, Joonatan (2019)
    Mixing processes under a seasonal ice cover in boreal lakes have received little attention from the physical limnological community. Even though the water is calm under the ice cover, many different phenomena are still able to cause mixing in the water column, which in turn affects the gas fluxes as well as physical and chemical properties of the water. Lakes in the boreal zone are very numerous. Understanding their behaviour helps us predict the effects of climate change in the boreal zone. In my thesis I present the various mechanisms that reign under the ice cover, and attempt to see these mechanisms in action in lake Kuivajärvi. Emphasis was placed on internal waves and the various components of the energy balance that can induce mixing. Data was collected with thermistor chains and a measurement raft between 24.1. – 3.5.2017. Two types of internal waves were observed during the ice-on season of 2016 – 2017. Short period barotropic seiches were observed during the whole ice-on season and transient long period baroclinic seiches were observed on two occasions. Other mixing processes seen in the lake were sediment heating in the dead of winter, penetrative convection caused by short wave radiation in the spring and diurnal stratification and mixing during spring caused by the daily heating and nightly cooling. Some mixing under the ice cover was found to depend on the meteorological conditions prevailing over the lake during the previous summer and just before the ice-on in late autumn, while others were more predictable. Long period internal waves and sediment heating are set in motion by meteorological conditions, while the spring mixing and overturn are more stable, due them being more a function of the orbital mechanics of our planet than the prevailing weather. Varying surface conditions of the lake ice cover make the measurement of especially the surface temperature complicated. Snow and ice are under a continuous metamorphosis due to the weather. This makes surface emissivity difficult to estimate, causing significant errors in the measurement of the outgoing longwave radiation. This in turn causes problems in defining the surface temperature from it. Also, the precipitation heat flux is difficult to estimate due to the lack of knowledge on the surface temperature.
  • Juurikkala, Kasper (2023)
    Clouds and aerosols are among the key components of Earth's energy budget, and a major source of uncertainty in climate models, affecting the predictability of the future climate. This thesis focuses on the microphysical processes governing cirrus clouds, wispy clouds composed of ice crystals. Understanding these processes is crucial due to the extensive global coverage of cirrus clouds and their potential warming effect on the atmosphere. The study investigates ice nucleation, the process by which ice crystals form in the atmosphere. Ice nucleation occurs via two main pathways: homogeneous freezing and heterogeneous nucleation. Homogeneous freezing is a process where droplets spontaneously freeze without an aid of an ice nucleating particle (INP). It occurs in highly supersaturated conditions and at cold temperatures below -38°C. Heterogeneous nucleation occurs when INPs act as surfaces to trigger freezing at temperatures below 0°C. The study is conducted using UCLALES-SALSA Large Eddy Simulation (LES) model, which offers high spatial and temporal resolution for atmospheric simulation. The aim is to investigate ice nucleation with five well-established parameterizations. Simulations produced with these parameterizations are compared with cirrus cloud properties measured during the MACPEX campaign. Among heterogeneous nucleation mechanisms, deposition ice nucleation is considered as a primary contributor to the formation of cirrus clouds in the upper troposphere and used as a mechanism to generate ice in the model study. Heterogeneous nucleation requires the presence of INPs which are assumed to be mineral dust is used as it known to dominate ice nucleation. Results show good agreement between modeled and measured data for ice concentration (Ni) and ice water content (IWC). The comparison between parameterizations revealed a relatively similar performance, with variations in Ni and IWC falling within the same order of magnitude. However, conclusive determination of the best-performing parameterization within the temperature and humidity ranges of the study was challenging. The study sheds light on the fundamental difficulties when using parameterizations with ice nucleation processes in cirrus clouds without accurate initial conditions and knowledge about the history of ice nucleation of the measured cirrus clouds. Also, the importance of proper validation of each parameterization by using different scenarios was emphasized.
  • Korhonen, Vesa (2023)
    Thawing of permafrost is widely observed, and its rate is expected to be accelerated due to the global warming caused by anthropogenic climate change. Although permafrost thawing has been acknowledged in IPCC Assessment reports, uncertainties related to model-based estimates of its extent and magnitude in the future exist due to the challenges for the models to account for heterogeneous changes in permafrost under the changing climate. Various one-dimensional finite element conductive heat transfer model codes have been successfully used for simulating permafrost, while models created with the COMSOL multiphysics tool have seen little use. In this work, COMSOL version 5.6 was chosen for modelling the heat transfer in permafrost. COMSOLs' ability to accurately simulate thermal evolution in porous medium experiencing freezing was demonstrated using the Interfrost test case T1, which is a benchmark modelling problem adapted to use by the Intercomparison project for TH (Thermo-Hydro) coupled heat and water transfers in permafrost regions. Benchmark results agreed with Lunardini's analytical solution, although compared to the previous studies, the results had more deviation from the analytical solution. Discontinuous permafrost in North-Western Siberia is thawing. Based on the temperature measurements available from three boreholes located in the area (Nadym), and an observed increasing mean annual air temperature trend of 0.5\textdegree C per decade, the rate of thawing could be increasing. A one-dimensional heat transfer model for one of the boreholes was created and benchmarked against soil temperature measurements to form a basis for future estimates of the permafrost evolution. The temperature time series produced by the model agreed moderately with the measurements, but the need for further model improvements was identified. Adjustments proposed in this work and parameter changes indicated by the sensitivity analysis form a basis for further model development. Additionally, the results of the conducted sensitivity analysis showed the importance of using accurate soil properties in modelling works.
  • Kröger, Anni (2019)
    Earth’s energy budget describes the balance between the net incoming and outgoing energy fluxes, and the energy balance approach can be used to better understand the basic physical mechanisms of climate change. Anthropogenic changes in the atmospheric composition, such as increases in greenhouse gases, drive changes in climate system which in turn can cause rising of the global temperatures. Various feedbacks, associated with increase in atmospheric water vapor content, changes in clouds and reduced snow/ice cover, affect the pattern of surface warming by altering the fluxes of energy. By studying the energy balance at the top of the atmosphere and at the surface, we gain useful information about the climate system’s response to changes in the atmospheric composition. In this thesis, data for 23 climate models in the fifth phase of the Coupled Model Intercomparison Project (CMIP5) was used. The present-day distributions and future projections of the simulated changes (under RCP8.5 emission scenario, Representative Concentration Pathway) for 14 radiative and non-radiative energy budget components, along with the changes in surface temperature and cloud cover were studied, with baseline period of 1981-2010 and a comparison scenario period of 2071-2100. The geographical distributions of the multimodel mean changes and their global averages were analysed. Additionally, the intermodel consistency of the simulated changes was studied with the intermodel standard deviations and the ratio of multimodel mean change to the intermodel standard deviation. Furthermore, the intermodel correlation between the change in surface temperature and each energy budget variable was discussed. A general finding was that the multimodel mean surface temperature increases everywhere, more over land than oceans, and that the warming is amplified over the northern polar regions. The changes were largest for the thermal radiation fluxes, and the dominating contribution to the surface warming was concluded to be the change in clear- sky atmospheric re-radiation component. However, increase in absorbed shortwave radiation, presumably due to reduced ice/snow cover and increase in atmospheric water vapor content, was also found to be substantial, and there was a strong negative correlation between the clear-sky downward shortwave radiation flux and the change in temperature over the low-to-mid latitudes. The comparison of contribution of the changes in longwave and shortwave fluxes to global warming in the near-future and long-term climate model projections could be an interesting subject for future studies. Additionally, the changes in the surface energy fluxes were found to modify the pattern of surface warming.
  • Kemppainen, Deniz (2023)
    The Arctic is warming approximately four times as fast as the rest of the planet, and the current and future changes may have drastic effects on the entire globe. However, the detailed processes of the Arctic climate have been studied to a small extent due to the remote and hard-to-reach location, and the representation of the Arctic in climate models has been inadequate. There are many uncertainties in climate models, and significant uncertainties concern aerosol-related information. Atmospheric aerosols have a large, yet not entirely understood and quantified effect on the climate. Aerosols affect the Earth’s radiative balance by scattering and absorbing incoming radiation, and they play a significant role in the cloud formation process. In order to improve the representation of the Arctic in climate models and tackle the unsolved questions about the Arctic atmosphere, sea ice, ocean, biogeochemistry and ecosystem, a one-year-long expedition called Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) was conducted in the central Arctic between September 2019 and October 2020. As secondary aerosol formation (new particle formation) produces more than 50% of the atmospheric cloud condensation nuclei, and iodic acid has been identified to be a significant compound for new particle formation in the Arctic pristine environments, the iodic acid concentrations during the full-year MOSAiC expedition was investigated. The main research objective was to quantify the seasonal cycle of iodic acid in the Arctic. The correlation with temperature, solar radiation and ozone were also studied. Together with ice dynamics, sea ice thickness and air mass back trajectory simulations, the possible sources of measured iodic acid were investigated. The participation in forming new particles was also studied. The measured iodic acid concentrations varied between 1e4 and 4e7 molecules/cm3 with a detection limit of 1.22e5 molecules/cm3, and the concentrations were in the same range with measured earlier in the Arctic. The highest concentrations were measured in April. An increased correlation of iodic acid concentration with temperature and radiation was observed during spring, and an anticorrelating trend was observed between iodic acid concentration and ozone during the period of high iodic acid, implying that iodic acid is partially responsible for ozone depletion in the arctic. Comparison with particle data showed that iodic acid concentrations measured during MOSAiC were sufficient to take part in the new particle formation. However, nucleation was not observed during the highest iodic acid concentration period in April.
  • Lehmusjärvi, Tuuli (2022)
    The effects of atmospheric aerosol particles on Earth’s radiative balance are mainly cooling, which is mostly due their indirect effects with clouds. In the Arctic more than half of the cloud condensation nuclei (CCN) production is originated from secondary aerosols, and to further the understanding of Arctic climate and its changes due to the global warming, it is necessary to better understand the secondary aerosol processes there. Highly oxygenated organic molecules (HOM) are known to be important for the formation and especially for the growth of newly formed secondary aerosols to climate relevant sizes. Because of the low volatilities of HOM, they can condense onto the smallest particles, which is crucial for the growth of the new particles. Volatile organic compounds (VOC), especially monoterpenes, are known to be sources of HOM in boreal forest, but in the Arctic where the vegetation is scarce the sources of HOM have not yet been identified. The processes related to secondary aerosol formation in the Arctic are still not fully understood. Especially the observations of HOM and their sources are lacking. Recent studies in Ny-Ålesund, Svalbard showed that multiple aerosol precursors are found to be present in the Arctic atmosphere, as well as contributing to the early stages of the formation of secondary particles. However, more molecular scale observations of aerosol precursors are still needed to form a full picture of the Arctic climate processes. In this thesis, the different aerosol precursors and their contributions to the new particle formations in high Arctic location Ny-Ålesund, Svalbard were analysed. Chemical compositions of HOM were identified for the first time from Arctic atmosphere, and their contributions to new particle formation in high Arctic location were investigated. Because of the high concentrations of HOM during the observed NPF events, it can be suggested that they were contributing to the nucleation of aerosol particles. Particle growth rate calculation shows that the HOM present in the study site were responsible for up to 50% of the total growth of the newly formed particles. VOC flux measurements done in same location were also analysed, and Arctic tundra in Svalbard was found out to be a source of at least four different VOC. Furthermore, the identified HOM were linked to the VOC flux measurements, suggesting a possible link between Arctic VOC and HOM.
  • Rautiainen, Laura (2020)
    Ocean reanalysis products (ORAs) can provide information on the state of the ocean. Although the different data sources, model configurations, forcing choices and assimilation methods cause the ORAs to deviate from each other, the ensemble approach has been previously found to produce realistic mean states. This raises the question if ORAs could be used for studying temporal and spatial changes in the Arctic Ocean, where measurements are generally sparse. Such study has not been previously published. In this thesis, the changes in the hydrography of the Arctic Ocean are examined over the previous decades based on selected ORAs. Eleven ORAs, TOPAZ4, C-GLORS025v5, ECDA3, GECCO2, GLORYS2v4, GloSea5-GO5, MOVE-G2i, ORAP5, SODA3.3.1, UR025.4 and ORAS5, were chosen for this study due to their overlap over 1993–2010 and the multimodel ensemble (MMM) was formulated based on the products, excluding ECDA3. The data were divided into depth layers and layer-average salinities and temperatures were used to calculate basin-average anomaly time series and trends to study the observed temporal changes. Per-grid trends were also produced to study both spatial and temporal changes in more detail. To assess their reliability, trends from the MMM and individual ORAs were compared to an observational product, EN4.2.0.g10 and the variability in the products and the MMM was assessed using statistical measures. The Eurasian Basin was found to be warming across all layers (up to 0.3 ◦ C decade −1 ) accompanied by salinification, except for localised cooling in the top 100 meters in the western basin, near the Fram Strait (-0.2 ◦ C decade −1 ). This indicates additional heat uptake by the surface 0–100 meters and also increasing heat and salinity content of the AW inflow, while the transport of sea ice out of the AO has increased. The Amerasian Basin, on the other hand, showed a strong freshening trend culminating at the Beaufort Gyre. This is most likely due to the anticyclonic wind forcing and increasing freshwater inflow to the Beaufort Sea. The Amerasian Basin also showed a warming trend in the 300–700 m layers but a cooling trend in the 100–300 m layer north of the Chukchi Sea. The ensemble approach worked well in dampening the extremities of singular ORAs, but some trends observed in the literature were missed due to disagreements between ORAs, especially in the Fram Strait and Beaufort Sea, which suggest that further improvements in both models and measurements are needed in those areas. Furthermore, improvements in deep ocean observations, how models handle the deeper ocean and assimilation methods are needed in order to study trends in the deeper depths in the AO. All in all, as the improvements come, the ORA MMM shows great potential for studies in the AO.
  • Feng, Weihang (2023)
    After 2013, the environmental protection department in China has significantly reduced on-road emission through the upgrade of emission standards, the improvement of fuel quality and economic tools. However, the specific effect of the control policies on emission and air quality is still difficult to quantify. This is mainly due to the data shortage on vehicle emission factors and vehicle activities. In this research, we developed the 2008-2018 on-road emissions inventory based on Emission Inventory Preparation Guide (GEI) and existing vehicle activity database. Our estimates suggest that CO and PM2.5 showed a relatively significant decrease, by 66.2% and 58.8%. However, the trend of NOx (5.8%) and NMVOC (-4.8%) was relatively stable. The Beijing-Tianjin-Hebei (BTH), Yangtze River Delta (YRD), Pearl River Delta (PRD) and Sichuan Basin (SCB) regions all showed a uniform trend especially in NOx. For Beijing-Tianjin-Hebei, the significant decline in NOx might be caused by earlier implementations in emission standard and fuel quality. In addition to this, we designed additional evaporation emission scenarios to verify the application of GEI in quantify emission impact on secondary pollutant (PM2.5 and O3). The results indicate that evaporation emission contributed to Maximum Daily Average 8-hour (MDA8) O3 concentration by about 3.5%, for Beijing, Shanghai and Nanjing. This value can reach up to 5.9%, 5.3% and 7.3%, but the impact on PM2.5is extremely limited. Our results indicate the feasibility of GEI in improving and lowering the technical barrier of on-road emission inventory establishment at the same time and its further application in quantifying on-road emission contribution to air quality. Besides that, it shows a strong potential in on-road policy environmental assessment and short-term air quality assessment.
  • Arola, Aleksi (2021)
    Freshwater ecosystems are an important part of the carbon cycle. Boreal lakes are mostly supersaturated with CO2 and act as sources for atmospheric CO2. Dissolved CO2 exhibits considerable temporal variation in boreal lakes. Estimates for CO2 emissions from lakes are often based on surface water pCO2 and modelled gas transfer velocities (k). The aim of this study was to evaluate the use of a water column stratification parameter as proxy for surface water pCO2 in lake Kuivajärvi. Brunt-Väisälä frequency (N) was chosen as the measure of water column stratification due to simple calculation process and encouraging earlier results. The relationship between N and pCO2 was evaluated during 8 consecutive May–October periods between 2013 and 2020. Optimal depth interval for N calculation was obtained by analysing temperature data from 16 different measurement depths. The relationship between N and surface pCO2 was studied by regression analysis and effects of other environmental conditions were also considered. Best results for the full study period were obtained via linear fit and N calculation depth interval spanning from 0.5 m to 12 m. However, considering only June–October periods resulted in improved correlation and the relationship between the variables more closely resembling exponential decay. There was also strong inter-annual variation in the relationship. The proxy often underestimated pCO2 values during the spring peak, but provided better estimates in summer and autumn. Boundary layer method (BLM) was used with the proxy to estimate CO2 flux, and the result was compared to fluxes from both BLM with measured pCO2 and eddy covariance (EC) technique. Both BLM fluxes compared poorly with the EC flux, which was attributed to the parametrisation of k.
  • Corner, Joona (2023)
    The aim of this work is to develop and optimise an atmospheric inverse modelling system to estimate local methane (CH4) emissions in peatlands. Peatlands are a major source of CH4 regionally in boreal areas and they have significance on a global scale as a soil carbon storage. Data assimilation in the inverse modelling system is based on an ensemble Kalman filter (EnKF) which is widely used in global and regional atmospheric inverse models. The EnKF in this study is an implementation of the EnKF used in the global atmospheric inversion model CarbonTracker Europe-CH4 (CTE-CH4) applied to local setting in the peatland. Consistency of the methodology with regional and global models means that it is possible to expand the system in scale. Siikaneva fen in Southern Finland is used as a testbed for the optimisation of the system. Prior natural CH4 fluxes in Siikaneva are acquired from the HelsinkI Model of MEthane buiLd-up and emIssion for peatland (HIMMELI) which simulates exchange of gases in peatlands. In addition to the peatland fluxes, anthropogenic fluxes at the site are estimated as well in the inversion. For the assimilation of atmospheric CH4 concentration observations, the CH4 fluxes are transformed into atmospheric concentration with a simple one-dimensional box model. The optimisation of the system was done by changing parameters in the model which affect the data assimilation. In model optimisation tests it was discovered that the performance of the modelling system is unstable. There was large variability in the produced estimates between consecutive model runs. Model evaluation statistics did not indicate improvement of the estimates after the inversion. No exact reason for the unstability was able to be determined. Posterior estimates of CH4 fluxes for years 2012–2015 did not differ much from prior estimates and they had large uncertainty. However, evaluation against flux measurements showed reasonable agreement and posterior concentration estimates were within the uncertainty range of the observed concentration.
  • Djupsjöbacka, Jemina (2024)
    Maaperän keskilämpötila on noussut viime vuosikymmeninä pohjoisilla alueilla kahdesta kuuteen kertaa muita leveysasteita nopeammin, ja muuttuvien lämpö- ja kosteusolosuhteiden myötä myös kasvihuonekaasupäästöissä on havaittu muutoksia. Erityisesti pohjoisten soiden päästöt ovat ajankohtainen tutkimusaihe. Viimeaikainen tutkimus korostaa suon pieneliöiden vaikutusta hiilipäästöihin ja ehdottaa, että eliöyhteisöjen muutoksilla voi olla aiemmin ymmärrettyä tärkeämpi merkitys päästöjen synnyssä. Tässä opinnäytetyössä tutkin kahden eliöyhteisön, sammalpunkkien ja kuoriamebojen, yhteyksiä suon vedenpinnan korkeuteen, lämpötilaan ja happipitoisuuteen sekä hiilidioksidi- ja metaaninvoihin. Erottelen mittauskammioiden vierestä ottamistani pintanäytteistä punkki- ja amebaesiintymät, ja vertaan niiden runsautta ja lajirikkautta ympäristö- ja kaasumuuttujiin. Tutkimuksessa huomaan, että kahden vierekkäisen suon lajisto ja ympäristö- sekä kaasumuuttujat ovat huomattavan erilaisia. Vertailen myös punkkien ja amebojen sopivuutta näiden muuttujien prokseiksi eli epäsuoriksi indikaattoreiksi. Amebat ovat paleoekologisessa tutkimuksessa vakiintuneempi eliöryhmä, mutta tutkimukseni pohjalta näyttää siltä, että myös punkkiyhteisöt voivat kertoa meille nykyisistä ja menneistä elinympäristöstä ja hiilipäästöistä. Punkkiyhteisöjen korrelaatio vedenpinnan korkeuden kanssa on liki samaa luokkaa kuin amebojen ja vedenpinnan korkeuden. Erityisesti kuivemman ja ravinneköyhemmän suotyypin metaanivoiden ja sammalpunkkiyhteisön välillä on merkittävä korrelaatio, ja tätä yhteyttä olisi jatkossa mielenkiintoista tutkia tarkemmin. Johtopäätöksenä esitän, että sammalpunkkien käyttö ympäristömuuttujien ja hiilivoiden proksina ja siirtofunktioiden kehittäminen punkkiyhteisöille voisi laajentaa paleoekologisen tutkimuksen näkökulmaa ja tuoda lisätietoa pieneliöyhteisöjen merkityksestä kasvihuonepäästöjen synnyssä.
  • Zhang, Jiangyi (2023)
    Ozone, an important and ubiquitous trace gas, protects lives from harm of solar ultraviolet (UV) radiation in the stratosphere but behaves as a toxic compound in the troposphere to living organisms. Also, tropospheric ozone is a vital oxidant or source of daytime oxidant (i.e., OH radical) for e.g., different volatile organic compounds (VOCs). Affecting global radiation balance directly or indirectly by acting as cloud condensation nuclei and having negative impact to human health, aerosols are widely studied for over a century. Highly oxygenated organic molecules (HOM) were proved to be a large source of secondary organic aerosol (SOA) and their oxidation formation pathways from VOCs can also trigger the production of ozone once involving NOx (=NO+NO2) and UV light. The highly nonlinear relationship among ozone, NOx, and VOCs (O3-NOx-VOC sensitivity or O3 formation sensitivity) has been researched since last century. The complex system was recently reflected during COVID-19 lockdowns: reduction of NOx increased the ozone production. This is because the system was in VOC-limited regime, where reducing VOCs is the most efficient way to reduce O3. However, the determination of O3 formation regimes (either VOC-limited or NOx-limited) is challenging in different environmental conditions. The intrinsic connection between HOM and O3 formation provide a new insight: the proportions of VOCs and NOx not only affect the O3 formation regimes but also impact the distribution of HOM species. Therefore, in this study, we try to unveil the indicating role of HOM species on the O3 formation sensitivity by chamber experimental works with a nitrate chemical ionization mass spectrometer (CI-APi-TOF) and gas monitors. Injected NOx and VOCs step by step, the experiments were designed to make the atmosphere-mimicking system change between those two regimes. The ratio between HOM-dimers and HOM organic nitrate monomers was selected as the indicator for O3 formation sensitivity due to their closely connected chemical reactions, involving peroxy radicals. Furthermore, a simple box model was developed for simulating chamber results and obtaining O3 isopleths to visually show the O3 formation regimes. Through experimental and model results, it can be inferred that ratios below 0.2 consistently correspond to the VOC-limited regime, whereas ratios above 0.5 consistently correspond to the NOx-limited regime. This study demonstrates that the ratio based on HOM species could additionally indicate the O3 formation sensitivity of ambient air when we use CI-APi-TOF to investigate the chemical compounds and aerosol formation, helping to elaborate the O3 pollution in the real troposphere.
  • Li, Xinyang (2020)
    The impacts of dust aerosols on human health and climate change are increasing as the particulate matter (PM) mass concentrations and frequency of Sand and Dust Storm (SDS) episodes have shown an increasing trend in recent studies, especially for the Middle East and North Africa (MENA). In this thesis, particulate matter (PM10 and PM2.5) concentrations were measured during May 2018–March 2019 in the urban atmosphere of Amman, Jordan. The PM sampling was 24-hours every 6 days. The overall mean PM10 mass concentration was 64±39 μg/m3 with the median (+interquartile range) value of 49.2+53.5 μg/m3, the PM2.5 mass concentration varied between 15 μg/m3 and 190 μg/m3 with an annual average 47±32 μg/m3 and with the median (+interquartile range) value of 35.8+26.3 μg/m3. The PM2.5 / PM10 ratio was 0.8±0.2. According to the Jordanian Air Quality standards, the annual mean PM10 needs to be below a limit value of 120 μg/m3, which was true in this work. However, the PM2.5 mass concentration was three times higher the corresponding limit value (65 μg/m3). However, both exceeded the World Health Organization (WHO) air quality annual guideline of 20 μg/m3 for PM10 and 10 μg/m3 for PM2.5. The results show that the observed PM10 mass concentrations in Jordan were lower than what was reported in other cities in the Middle East but were higher when compared to other Mediterranean cities. During the measurement period, Jordan was affected by Sand and Dust Storms (SDS), which were observed on 14 sampling days. The source origins of these SDS were traced back to North Africa, the Arabian Peninsula, and the Levant. The 24-hour PM10 concentrations during these SDS episodes ranged between 108.1 μg/m3 and 187.3 μg/m3. In the future, measurements with a higher time resolution (one sample per day) are recommended for a more precise seasonal trend interpretation.
  • Turunen, Tarja (2023)
    Norway spruce (Picea abies (L.) Karst.) is one of the economically most important tree species in Finland. It is known to be drought-sensitive species and expected to suffer from the warming climate. In addition, warmer temperatures benefit pest insect Eurasian spruce bark beetle (Ips typographus L.) and pathogen Heterobasidion parviporum, which both use Norway spruce as their host and can make the future of Norway spuce in Finland even more difficult. In this thesis, adult Norway spruce mortality was studied from false colour aerial photographs taken in years between 2010 and 2021. Dead trees were detected from the photos by visual inspection, and mortality was calculated based on the difference in the number of dead trees in the photos from different years. The aim was to find out if Norway spruce mortality in Finland had increased over time, and what were the factors that had been driving tree mortality. The results indicate that tree mortality was the highest in the last third of the studied 10-year period, so it was concluded that tree mortality had increased over time. Various possible tree mortality drivers were analysed and found to be connected to tree mortality. Each driver was analysed individually by testing correlation with tree mortality. In addition, linear regression analysis and segmented linear regression with one breakpoint were used with the continuous variables. Increased tree mortality correlated with higher stand mean age, mean height, mean diamater, and mean volume, supporting the findings in earlier research. Mortality was connected to the proportion of different tree species in the stand: the higher the proportion of spruce, the higher the mortality, and the higher the proportion of deciduous trees, the lower the mortality. Of different fertility classes, tree mortality was the highest in the second most fertile class, herb-rich heat forest, and mortality decreased with decreasing fertility. Dead trees were also found to be located closer to stand edges than the stand centroid. Increased temperature resulted in increased mortality. Increased vapour pressure deficit (VPD) and drought, which was analysed with Standardized Precipitation Evapotranspiration Index (SPEI) of different time scales, were also connected with increased tree mortality. Further research is required for understanding and quantifying the joint effect of all the interacting mortality drivers. Nevertheless, it seems that for Norway spruce, the warmer future with increased mortality is already here, and it should be taken into consideration in forest management. Favouring mixed stands could be one of the solutions to help Norway spruce survive in the warming climate.
  • Mahó, Sándor István (2021)
    This thesis analyses the alterations of vertically integrated atmospheric meridional energy transport due to polar amplification on an aqua planet. We analyse the energy transport of sensible heat, latent energy, potential energy and kinetic energy. We also cover the energy flux of the mean meridional circulation, transient eddies and stationary eddies. In addition, we also address the response of the zonal mean air temperature, zonal mean zonal wind, zonal mean meridional wind, zonal mean stream function and zonal mean specific humidity. Numerical model experiments were carried out with OpenIFS in its aqua planet configuration. A control (CTRL) and a polar amplification (PA) simulation was set up forced by different SST (sea surface temperature) patterns. We detected tropospheric warming and atmospheric specific humidity increase 15-90° N/S and reduction of the meridional temperature gradient throughout the troposphere. We also found reduced strength of the subtropical jet stream and slowdown of the mean meridional circulation. Important changes were identified in the Hadley cell: the rising branch shifted poleward and caused reduced lifting in equatorial areas. Regarding the total atmospheric vertically integrated meridional energy transport, we found reduction in case of the mean meridional circulation and transient eddies in all latitudes. The largest reduction was shown by the Hadley cell transport (-15%) and by midlatitude transient eddy flux (-23%). Unlike most studies, we did not observe that meridional latent energy transport increases by polar amplification. Therefore, it is stated that the increased moisture content of the atmosphere does not imply increased meridional latent energy transport, and hence there is no compensation for the decrease of meridional dry static energy transport. Lastly, we did not detect stationary eddies in our simulations which is caused by the simplified surface boundary (i.e. the water-covered Earth surface). The main finding of this thesis is that polar amplification causes decreasing poleward energy transport on an aqua planet.
  • Al Dulaimi, Qusay (2020)
    Sand and dust storms are one of the major regional environmental problems that affect human health. Many environmental studies have focused on airborne dust concentrations observed at different regions and have tried to connect the observations to specific dust source regions. This thesis aims to provide a new dust classifications scheme for the Eastern Mediterranean region, specifically observed in Amman, Jordan. I utilized a combination of a long-term data-base consisting of aerosol particle number concentration in coarse mode (1–10 µm) during November 2013 – July 2018 and air mass back trajectories analysis to visually identify the Sand and Dust Storm (SDS) episodes. The classification included three main source regions of for the submicron dust, namely Sahara, Arabia, and Levant. I also classified the data according to the, episode intensity according to their corresponding number concentrations as no-dust, mild, intermediate, and strong intensities and further classified the range of back trajectories as short, intermediate, long, and very long, which indicates the distance between the observation site and the source region.. The results showed that majority of the dust events and an elevated number of dust days are influenced by a source in Levant and Sahara source region. These events which dominated during 70 days in 2016. The Levant source governed during 60 days during the same period. Other dust sources contributed less to the dusty days, and the lowest dusty days number was due to emissions from Levant & Arabia (19 days). The episode intensity varied censurably and underlined variability from the different source areas. The maximum intensity in the dust episode concentration was linked to Levant & Sahara with a max number concentration of 95 /cm3. The classification method was successful and it was able to establish a dust source database in the Eastern Mediterranean region based on the long-term observations performed in Amman with variable dust concentration and dust periods in different seasons and different meteorological circumstances.
  • Uusinoka, Matias (2022)
    Sea-ice dynamics is becoming increasingly essential for the modelling warming climate as the extent and thickness of the ice cover are decreasing along with increasing drift speeds and mechanical weakening. The description of the sea-ice dynamics involves an enormous variety of spatial and temporal scales from meters to the scale of the Arctic Basin and from seconds to years in the geophysical approaches. The complex coupled spatio-temporal scaling laws prohibit the commonly utilized procedures for scale linkage of ice mechanics. Currently, deformation scaling presents one of the principal open questions in sea ice dynamics for which the thesis aims to provide observational analysis. The high-resolution ship-radar imagery gathered during the MOSAiC expedition from October 2019 to September 2020 for which deformation component rates were calculated to generate a seasonal deformation time series. Current research of deformation scaling commonly relies on satellite imagery and drift buoys for which the spatial and temporal resolutions often tend to be considerably lower than for the ship-radar data. The formerly observed dominant deformation mode of shear and the strong spatial correlation of divergence and shear in the Arctic sea ice were confirmed with no signs of seasonal variation. The temporally averaged deformation variations were found to coincide with satellite derived deformation events rather poorly. A strong length scale dependence of deformation was confirmed in the ship-radar data. The spatial scaling law exponents were found to show unexpectedly high values with the behaviour of both spatial and temporal scaling law exponents disobeying the previously observed large-scale characteristics. The seasonal variation of both scaling law exponents were found to exhibit the commonly observed trends following the progression of total deformation rate. The obtained results showed unexpected values and behaviour for the deformation scaling law exponents, which was suggested to be due to the technical faults in the ship-radar data. The faults were often spatially local and lasted merely for a single time step leading to a possible increase in the localization and intermittency of the deformation rates. Additionally, the new ice conditions of the Arctic Ocean and drift route along the Transpolar Drift were suggested as a possible physical source of the unexpected results. Further studies with different methodologies were suggested for the verification and possible the dismissal of the unexpected results.