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Browsing by discipline "Geologi"

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  • Kuikka, Jaro (2018)
    The Archean Hattu schist belt in eastern Finland is host to several orogenic gold occurrences. One of these deposits is the Pampalo gold deposit located in Hattu, Ilomantsi. Major and trace element characteristics of biotite and chlorite were analyzed from a representative collection of rock types of different degrees of alteration from the Pampalo deposit. The main aim of this study was identifying possible correlation of changes in the elemental composition of biotite and chlorite with distance to gold ore mineralization and testing the two minerals’ use as proxies for mineralization in Pampalo. Biotite and chlorite were chosen for being represented in altered and unaltered ore and adjacent country rock units. Samples were prepared from half and quarter drill core rocks and analyzed with hyperspectral imaging, electron micro probe analysis (EMPA) and laser ablation inductively coupled plasma mass spectrometer (LA-ICP-MS). Hyperspectral imaging and thin section microscopy were used for mineral identification and mineral grain sampling. EMPA and LA-ICP-MS data found weak correlation with distance to mineralization for Mg, Al, Ti, Fe, Zn, Sr and Cs in biotites and Li, B, Mg, Al, Si, P, Sc, Ti, Mn, Fe, Ni, Zn, Ga, As and Sr for chlorite. Moderate correlation was found for Pb and Tl in biotites and Co in chlorites. Strongest correlation was found for Mn, W and Ba in biotites. These three elements all deplete in biotites with decreasing distance to mineralization. Changes in concentrations of manganese are likely variation in host rock chemistry. Tungsten concentrations seem to be linked to fluid flows, but only indirectly related to gold ore mineralization. Barium was found to be the most promising element within biotites due to its high mobility, and its depletion could indicate approaching gold ore mineralization. Changes in As concentrations of chlorites also point to two different types of chlorite grains, one of which indicate an ore mineralization event having taken place.
  • Kähkönen, Aili (2014)
    Puhtaan veden saanti on elinehto. Vesihuolto olisi suunniteltava pahimman skenaarion varalta, koska sen asema keskinäisriippuvaisessa yhteiskunnassa on hyvin keskeinen. Vesihuoltolaitosten toimintavarmuuden parantamisen, pullotetun veden käytön, siirrettävien vesisäiliöiden käytön ja kotitalouskohtaisen pintaveden puhdistuksen lisäksi valmiutta kohotettaessa voitaisiin hyödyntää Suomen ainutlaatuisia pohjavesivaroja. Matalakairauksen avulla tehtyjä havaintoputkikaivoja voidaan käyttää juomavedenhankinnassa. Kairaaminen ulotetaan maksimissaan kuuden metrin syvyyteen, jotta maan pinnalla pidettävän imupumpun teho riittää pohjaveden ottamiseen. Menetelmää on käytetty pääasiassa pohjavesinäytteiden keräämiseen ja antoisuusmittauksien tekemiseen. Sen lisäksi Puolustusvoimat on ottanut matalakairauksen osaksi vesihuollon järjestelyjään kriisiaikana. Ympäristöalalla kerätään runsaasti tietoa erilaisiin paikkatietokantoihin, arkistoihin ja tutkimushankkeisiin. Näiden hyödyntäminen poikkeusolojen vesihuollon suunnittelussa vaatii tiedon poimimista ja yhdistämistä. Ennakkoon erotelluilla aineistoilla voidaan parantaa valmius-suunnittelua ja vähentää asiantuntijoiden tarvetta yhdyskuntien kriisinajan vedenjakelun turvaamisessa. Soranottoalueiden tilaa ja kunnostustarvetta arvioivassa hankkeessa (SOKKA) on koottu maa-aineksen otossa olleita kohteita, jotka ovat pohjavesialueilla. Näissä voitaisiin olettaa löytyvän lähellä maanpintaa olevaa pohjavettä. SOKKA-hanke on valtakunnallinen ja kaikkiin siinä oleviin kohteisiin pääsee ajoneuvoilla. Tässä työssä yhdistettiin olemassa olevaa tietoa Etelä-Pohjanmaan ELY-keskuksen SOKKA-hankkeen paikkatietoihin ja pyrittiin arvioimaan, kuinka hyvin niiden avulla voitaisiin varmistaa kohteiden soveltuvuus matalakairaukseen. Tavoitteena on saavuttaa yksinkertainen tulos, jonka avulla voidaan todeta että näistä kohteista saadaan luotettavasti vettä mahdollisissa poikkeusoloissa. Kohteista pyritään muodostamaan verkosto, joka on kattava, ja joka voitaisiin laajentaa valtakunnalliseksi. Tulokset osoittavat että matalakairaukseen soveltuvien kohteiden verkosto on mahdollista muodostaa olemassa olevan tiedon avulla. Tässä työssä käytettyjen aineistojen avulla kohteet karsiutuvat alkuperäiseen aineistoon verrattuna harvalukuiseksi, mutta verkosto on kuitenkin maantieteellisesti kattava.
  • Vaittinen, Tiina (2014)
    Dredging of the seafloor is often a prerequisite for keeping seaways and harbours operational in the coastal area of Finland. This leads to a need to transport and dispose of the dredged material, which in turn creates environmental concerns. The influences of sea disposal can usually be clearly observed during the process. There has not been as much research on the long term effects, due to difficulties in observing material at the bottom of the sea and in separating the effects of sea disposal from background conditions and other changes that might have taken place in the area. The objective of this study is to gather research data to help in assessing the effects of sea disposal and defining the preconditions for environmentally sustainable disposal projects. The research focuses on two disposal sites for soft dredged material, located in Naantali and Hamina. The site in Naantali is very close to the mainland and a busy harbour, with heavy sea traffic. The site in Hamina is in a location with markedly calmer current conditions, within a scarce archipelago. The effects of the sea disposal were examined three years after the disposal operation. Special attention was paid to how well the disposed material had remained at the disposal sites. Surface sediment samples were taken from both study areas. Based on sedimentation signals observed in these samples, the study aims to determine how well the disposed material had remained in place. The movements of the material were also assessed by observing the topographical changes that had taken place at the sites over three years. The study additionally utilizes monitoring reports and previous research to assess the identified effects on the environment and the factors that influence them in the context of the Baltic Sea area. According to the results, the disposal site at Hamina is an exemplary one, because the disposed material has settled and become part of the existing seafloor. The material is also physically of a superior quality to the original surface sediment, which suffered from oxygen depletion. Sea disposal has managed to isolate the original, heavily oxygen consuming layer of sulphide mud from the bottom water. At the Naantali site, the disposed material appears to have stabilized rather well, but the result is not as obvious as at Hamina. This is largely due to the strong slipstreams in the area causing resuspension of the surface mud. Furthermore, characterization of the disposed material was relatively difficult at the Naantali site due to the strong physical resemblance between original and disposed sediment. Surface sediment samples and basic physical characterization proved to be a useful method in researching the settling of disposed material. When looking for possible signs of sedimentation, the topmost surface layer of samples is especially important. Depth data can also be used in monitoring disposal sites, although based on depth data alone it is difficult to draw conclusions on the reasons for changes in topography.
  • Uuttu, Petri (2014)
    The Paleoproterozoic volcanically hosted massive sulfide deposits of the Skellefte district, northern Sweden has been subjected to regional metamorphism in greenschist to amphibole facies conditions at 1.84 – 1.82 Ga, resulting in the remobilization of ore minerals and formation of ore-bearing quartz and sulfide veins. The aim of this project is to study the mineralogy and mineral chemistry of the Storliden VHMS deposit in the Skellefte district and determine the conditions the remobilization of ore minerals took place in. The sulfide-rich remobilization veins in the deposit consist of two types: ones composed mostly of pyrrhotite and chalcopyrite, and ones composed mostly of galena and bournonite, often as symplectitic intergrowths, with gudmundite and tetrahedrite occurring in notable amounts as well. Arsenopyrite and sphalerite were found in multiple veins of both types. Additionally, sulfide-poor quartz- and calcite veins occur in the deposit. There are also sulfide-bearing calcite veins that post-date the metamorphism, and were not included in this study. Sphalerite and chlorite from the veins both have lower Fe-content than same minerals in the massive ore and the host rock of the ore, respectively. Sphalerite form the veins also has a significantly higher Cd-content compared to the massive ore. The tetrahedrite from the veins also has a clearly different composition than in the massive ore, with considerably lower As-content and higher Fe/(Fe+Zn) ratio. Arsenopyrite geothermometry was used to determine that the remobilization took place at temperature of 325 – 480 °C, with mean T of 425 °C for the massive ore and 412 °C for the remobilization veins. The composition of sphalerite from the massive ore was used to determine that the pressure during metamorphism was 6.3 – 8.5 kbar, with mean of 7.5 kbar. Thermometric data obtained from chlorite in the quartz veins and the host rock of the ore indicates lower temperatures than the data from arsenopyrite, with mean T of around 200 °C or less for the veins and around 300 °C for the host rock (exact temperature depending on the geothermometer used). The lower range of temperatures likely reflects formation or re-equilibration during the retrograde stage of the metamorphism. The δ18O-data for water calculated from the quartz veins range from 4.7 to 8.8 ‰ with mean δ18O of 7.2 ‰, which is within the δ18O-range of metamorphic water. The values for pressure and temperature obtained conform to data reported by other authors from various deposits in the Skellefte district, which mostly fall between temperatures of 300 – 500 °C and pressures of 5 – 8 kbar for the massive ore, and 200 – 450 °C and 0.5 – 5 kbar for the veins. The δ18O-data is likewise within the range reported from quartz veins elsewhere in the Skellefte district (ranging from 3.7 to 11.6 ‰).
  • Hicks, Matthew (2015)
    The late Archean Hattu schist belt, located within the Ilomantsi greenstone belt, formed at approximately 2750 Ma and is composed of felsic volcanic and epiclastic deposits and hosts multiple diverse orogenic-style gold deposits. The Korvilansuo prospect is located within the southern portion of the schist belt and is situated between the Kuittila tonalite and the Silvevaara granodiorite intrusions. The deposit hosts hydrothermally-altered gold-bearing quartz-tourmaline veins located near the Korvilansuo shear zone. Korvilansuo is enriched in important ore minerals and metals such as gold, sulfides, and tellurides. A combination of structural, metamorphic and hydrothermal events occurring within the region contributed to mineralization of the deposit. The metamorphic grade of the deposit reached the upper greenschist to lower amphibolite facies based garnet-biotite geothermometry indicating peak temperatures of 570 ± 30 °C. Pressures of 2.9 – 4.2 kbar occurred at Korvilansuo at peak conditions. Hydrothermal alteration is highly prevalent within tonalite and mica schists. Extensive structural deformation is visible as the deposit lies within the brittle-ductile transition zone. Gold appears throughout the deposit, occurring in fractures of tourmaline-quartz veins, as well as disseminated throughout the mica schist samples alongside sulfides and as telluride compounds. Sulfides encountered in the Korvilansuo area include: pyrite, pyrrhotite, chalcopyrite, gersdorffite, arsenopyrite, and other minor phases. Tellurides occur primarily as tsumoite and other telluride minerals occur as residual disseminated phases within pore spaces. Three main fluid types are found within the deposit consisting of high-vapor, high salinity (approximately 27.7 wt. % NaCl), and low-salinity, aqueous-carbonic fluids. Vapor-rich fluids are the oldest, while the NaCl-rich inclusions were determined to be older than aqueous-carbonic fluids and may be responsible for transporting ore. Homogenization temperatures of the late low-salinity, aqueous-carbonic fluids are approximately 323 °C, with hydrothermal chlorites recording mineralization temperatures of up to 450 °C. Temperatures therefore suggest that mineralization occurred after peak metamorphic conditions.
  • Luoto, Toni (2018)
    Yeniyaylacık and Sofular localities in southeast of Central Anatolia are yielded with rich and wellpreserved late Neogene mammal fossils including bovids, equids, suids and rhinos. Faunal compositions of these sites are distinct from each other and biostratigraphy is still under study. The age and correlation of the Sofular ignimbrite underlying the studied Sofular section has been contentious in previous studies. For Yeniyaylacık section there are no previous detailed ages published. In this study, the magnetostratigraphic results are presented for the Yeniyaylacik and Sofular sites. The sampled Sofular section (located in 38°43’35” N, 35°00’30” E) is overlaying the Sofular Ignimbrite. In total 83 samples were taken from this ca. 51-meters-thick section, which is composed of thinly bedded and laminated siltstones and siliceous claystones with a few sandstone intercalations. Upper parts are more calcareous and dominated with limestone and claystone beds containing gypsum crystals. In total 32 samples were taken from ca. 8-meters-thick Yeniyaylacık section (located in 38°45’35” N, 34°37’04” E), comprised of muddy-clayey sediments with few thin limestone-sandstone units interbedded in the succession. Grain size of the samples was estimated based on Udden-Wentworth scale and color based on Munsell color chart. Carbonate content of the samples was estimated using 10 % hydrochloric acid. Magnetic susceptibility of each sample was measured using SM 150 susceptibility meter. 2G SQUID magnetometer was used to stepwisely demagnetize the samples. Thermomagnetic analyses were done using KLY-3S kappabridge for selected samples to identify magnetic mineralogy of the sections. Rock magnetic studies revealed that samples located at higher levels were clearly less magnetic in both of the sections, which correlates well with the increased carbonate content. Magnetic mineralogy of the samples consists mostly of Ti-poor titanomagnetite, but some of the samples also contained some hematite. AF-demagnetization results indicated that reversed polarity dominates the lower ca. 15 m in the Sofular section. The upper 35 m of the section is dominated by normal polarity. In the Yeniyaylacık section, reversed polarity dominates the whole section. Based on earlier studies and paleomagnetic results from this study, correlation with chron C4n.2n (8,1–7,7 Ma) or C3An.2n (6,7–6,4 Ma) is suggested for the long period of normal polarity in Sofular section. Less derived morphology of the Yeniyaylacık fauna suggests older age for the Yeniyaylacık fauna, so correlation with chron C4r (8,8–8,1 Ma) is suggested for long period of reversed polarity in the Yeniyaylacık section.
  • Turunen, Sanni (2015)
    This study describes a series of picritic lavas from the Luenha River, Mozambique, related to the Karoo large igneous province. The reservoirs for the African Karoo-related flood basalts are not well known. There are no previously documented primitive volcanic rocks related to them. In this study, picritic lavas from the Luenha River are found to be primitive and to exhibit a HREE-undepleted trace element signature, similar to those of African flood basalts. Significant within-series variation is observed in REE concentrations and Sr isotopic compositions, and can be modelled as a result of crustal contamination of a primitive melt. The high deltaNb values (0,4–0,6), low TiO2 concentrations (0,3–1,0 wt. %), high-Al spinel cores, chondritic isotopic ratios in the most primitive samples and smooth, HREE-undepleted PM-normalized trace element compositions could be derived by high-degree, shallow depth partial melting of a source other than depleted upper mantle. Luenha picrites might represent a parental melt for the Karoo shallow source lavas and may facilitate characterization of their mantle sources. Major element compositions were analysed by X-ray fluorescence method (XRF), trace elements by inductively coupled plasma mass spectrometer (ICP-MS), mineral chemistry by electron probe microanalyzer (EPMA) and isotopic ratios for Sr and Nd were measure with thermal ionization mass spectrometer (TIMS). A polarization microscope was used for petrography.
  • Karinen, Jouko (2013)
    Mustaliuskeet ovat tummia ja helposti rapautuvia sedimenttikiviä, jotka sisältävät runsaasti hiiltä ja metallisulfideja. Niiden rapautuessa ympäristöön vapautuu metalleja ja vetyioneja. Turpeen on todettu sitovan tehokkaasti eri alkuaineita ja läheisestä kallioperästä rapautuneet metallit pidättyvät usein turpeeseen. Talvivaaran mustaliuskeisiin on rikastunut Co, Cu, Mn, Ni ja Zn, ja esiintymälle on tunnusomaista kohonnut Ni-pitoisuus. Mustaliuskealueiden moreeneista on mitattu korkeita Cu- ja Zn-pitoisuuksia, ja pintavesille on tyypillistä alhainen pH ja kohonneet Cd-, Cu-, Mn-, Ni- ja Zn-pitoisuudet. Liuskealueilla myös kaivovesistä ja purosedimenteistä on mitattu kohonneita pitoisuuksia samojen alkuaineiden osalta. Tähän tutkimukseen koealoilta otettiin turvenäytteitä, joista määritettiin turvelaji, maatuneisuus ja sähkönjohtavuus. Laboratoriossa näytteistä määritettiin tuhkapitoisuus TGA-menetelmällä ja kokonaishiilen määrä CHN-menetelmällä. Näytteille tehtiin myös monialkuaineanalyysit ICP-MS (503M)- ja ICP-AES (503P)- menetelmillä, ja Hg- pitoisuus määritettiin CVAFS-analyysillä. Tuloksista laskettiin pistekohtaisesti painotetut keskiarvot ja -hajonnat, sekä koealakohtaisesti Spearmanin korrelaatiokertoimet PASW Statistics 18-ohjelmalla. Osalle aineistosta tehtiin regressioanalyysi. Kartat tehtiin ArcGIS10-ohjelmistolla Geologian tutkimuskeskuksen ja Maanmittauslaitoksen kartta-aineistojen pohjalta. Mustaliuskealueilla turpeiden keskimääräiset Al-, As-, Cd-, Co-, Fe-, Mn-, Ni-, S-, Zn- ja tuhkapitoisuudet ovat huomattavasti korkeammat kuin granitoidi- ja kvartsiittialueilla, kun taas Cu- ja U-pitoisuudet ovat mustaliuskealueilla huomattavasti alhaisemmat. Tuhka- ja alkuainepitoisuudet ovat kvartsiitti- ja granitoidialueilla kohonneita lähinnä pohjanäytteissä, kun taas mustaliuskealueilla monien alkuaineiden pitoisuudet ovat korkeita myös pintanäytteissä. Parhaimmat riippuvuudet havaittiin Cu- ja U-pitoisuuksien, sekä Cr- ja tuhkapitoisuuksien välillä. Mustaliuskealueilla merkittäviä riippuvuuksia oli havaittavissa As-, Fe-, S- ja tuhkapitoisuuksien välillä, mikä voisi olla yhteydessä mustaliuskeiden rautasulfideihin. Poikkeuksellisesti yhdellä kvartsiittialueen koealalla alkuainepitoisuudet muistuttivat mustaliuskepisteitä. Tämä saattaa johtua osaltaan voimakkaasta reunavaikutuksesta, mutta koealalle on myös saattanut kulkeutua mustaliuskepitoista materiaalia jäätikkökuljetuksen seurauksena. Eräällä mustaliuskekoealalla alkuainepitoisuudet ovat sitä vastoin poikkeuksellisen alhaisia. Tämä johtunee turpeen rahkavaltaisuudesta, heikosta kontaktista kallioperään tai sijainnista vedenjakaja-alueella. Mustaliuskealueilla turpeiden alkuainepitoisuudet näyttäisivät olevan suurelta osin yhteydessä Talvivaaran mustaliuske-esiintymän koostumukseen, ja joillakin tutkimuspisteillä erilaiset mustaliuskeiden mineralisaatiot voisivat kuvastua anomaalisina Mn-, Ni-, Zn- ja Fe-pitoisuuksina. Turpeen kemialliseen koostumukseen saattaa kallioperän lisäksi vaikuttaa erilainen turvelajikoostumus mustaliuske- ja granitoidipisteiden välillä, voimakkaampi reunavaikutus mustaliuskekoealoilla, tulvavaikutus tai tien läheisyys. Lisäksi joillakin alkuaineilla epävarmuutta voi aiheuttaa niiden geokemiallinen luonne. Ympäristössä Cu lähtee heikosti liikkeelle ja se pidättyy nopeasti humukseen. Siten Cu ei välttämättä ehdi kulkeutua kallioperästä turpeeseen asti. Zn sitä vastoin on hyvin liikkuva, mutta se pidättyy heikosti turpeeseen. Jatkotutkimuksissa kannattaisi tarkastella keskenään mahdollisimman samankaltaisia turvemaita, jotka eivät ole altistuneet ihmistoiminnalle, tulville tai muille ulkoisille häiriötekijöijlle.
  • Aksola, Aleksanteri Mitja (2016)
    The research material consists of 21 dolomite samples taken from the Kalvberget formation in western Sweden. δ13C and δ18O values were analysed from these samples, as well as trace elements and REE composition. Analysis was performed using IRMS, XRD and ICP-MS methods. Main function of trace elemental analysis was to conclude if the isotopical values represented primary marine values or if these values were changed during metamorphical processes. Main question in this thesis was to find out if these samples represented Neoproterozoic cap carbonates and how these samples fit in the global Neoproterozoic δ13C graph. The samples had undergone a green schist-amphibolite facies metamorphosis. The samples were gathered around the Kalvberget formation, representing approx. 30 m of the outcrop. Samples represented thickness of 15 m from the outcrop. Samples K1-K6 had metamorphosed more clearly than samples K7-K21. This was found out from the trace elemental composition. Samples K1-K6 had reacted with silicates, thus changing their primary composition of δ13C and δ18O towards a more negative value. δ13C values of samples K1-K6 were between -3,07 ... -3,34‰ and δ18O values were between -12,04 ... -12,59‰. Samples K7-K21 had δ13C values between +2,07 ... +4,42‰ and δ18O values between -5,94 ... -8,59‰. Indication of metamorphosis affecting the isotopic values in samples K1-K6 led to removal of these samples from the isotopic examination. Samples K7-K21 thus represent primary marine values better. Samples K7-K21 had signs of δ18O values changing because of the interaction with fluids, but the δ13C values represented almost constant values. REE composition showed some signs of detrital matter in the silicate rich samples. Part of the samples were left out from the REE composition examination, as they represented more PAAS content and not primary marine values. Because silicate concentration clearly affected the REE concentrations, all samples with less than 85% carbonate were left out from the REE examination. With these restrictions only samples K7, K11-K16, K18 and K20 were left from examination. REE plots of these samples resembled modern seawater REE plots, although the samples were depleted in HREE compared to modern seawater. From the Ce/Ce* anomaly it was concluded that these samples formed in anoxic environment. Mean value for Ce/Ce* anomaly was 0,94, which differed greatly from modern values. Samples K7-K21 were plotted in global Neoproterozoic δ13C plot. In the plot they placed between the Marinoan and Sturtian iceages 700 – 650 Ma. Conclusion from these results is that these samples do not represent typical cap carbonates formed in Neoproterozoic glaciations, but they are carbonate sediments formed in marine environment between the iceages.
  • Lammi, Hannu (2015)
    This work explores the lateral spreading of hot, thick, Paleoproterozoic crust via a series of 2D thermomechanical numerical models based on two geometrical a priori models of the thickened crust: plateau and plateau margin. High Paleoproterozoic radiogenic heat production is assumed. The material viscosity is temperature-dependent following the Arrhenius law. The experiments use two sets of rheological parameters for the crust: dry (granite/felsic granulite/mafic granulite) and wet (granite/diorite/mafic granulite). The results of the modeling are compared to seismic reflection sections and surface geological observations from the Paleoproterozoic Svecofennian orogen. Numerical modelling is performed with Ellipsis, a particle-in-cell finite element code suitable for 2D thermo-mechanical modelling of lithospheric deformation. It uses Lagrangian particles for tracking material interfaces and histories, which allow recording of material P-T-t paths. Plateau-models are based on a 480 km long section of 65 km-thick three-layer plateau crust. In the plateau margin-models, a transition from 65 km thick plateau to 40 km thick foreland is imposed in the middle of the model. The models are extended symmetrically from both ends with slow (1.9 mm/a) and fast (19 mm/a) velocities. Gravitational collapse is simulated with an additional set of fixed boundary plateau margin models. The models are studying the effect of free moving boundaries on the crustal structure and the conditions for mid-crustal flow. Strong mid-crustal channel flow is seen in plateau margin models with dry rheology and slow extension or with fixed boundaries. With fast extension or wet rheology channel flow grows weaker/diminishes. In models with slow extension or fixed boundaries, partial melting controls the style of deformation in the middle crust. Vertical movement of the partially molten material destroys lateral flow structures in plateau regions. According to P-T-t paths, the model materials do not experience high enough temperatures to match HT-LP metamorphic conditions typical for Svecofennian orogenic rocks. Metamorphic conditions in the dry rheology models have counterparts in the LT-LP (>650 °C at ≤600 MPa) amphibolite facies rocks of the Pielavesi area. Plateau margin models with dry rheology and slow extension or fixed boundaries developed mid-crustal channel flow, thinning of middle crust, exhumation of mid-crustal domes and smooth Moho, all of which are found in crustal scale reflection sections. Results of this work suggest plateau margin architecture prior to extension that took place at slow velocities or through purely gravitational collapse, although peak temperature of Svecofennian HT-LP metamorphism was not attained.
  • Kähkölä, Noora (2015)
    Peatlands influence the atmospheric circulation of carbon dioxide and methane. Because of changing climate, there is a growing interest to study northern peatlands, because they contain up to one-third of the total pool of soil carbon. Climate change is expected to be strongest in the high-latitudes. The prediction is that in the north a rise in the temperature is highest and the changes in precipitation are most pronounced. The purpose of this study was to examine mire development and carbon dynamics of one forestry-drained ombrotrophic mire. The aim was to determine vegetation history, changes in peat and carbon accumulation patterns and the effects of drainage on mire development. The research material consisted of peat samples collected from Kalevansuo. The vegetation development was examined by using macrofossil analysis and correspondence analysis (CA). Peat properties, such as LOI and bulk density, were also studied. The studied peat cores were radiocarbon dated. Flux measurement data on greenhouse gases were also used to interpret data. Kalevansuo started to develop more than 10,000 years ago through terrestrialisation. The development includes an initial fen phase followed by a cotton grass phase which changed further to a Sphagnum phase. The top peat layers represent drainage-affected phase. The fen-bog transition occurred around 4,100 years ago. Kalevansuo expanded to its southern margins about 5,200 years ago whereas lateral expansion in the east has been an ongoing process even after 1950. Peat and carbon accumulation has been slow when compared to some other bogs in the southern Finland. As a result of drainage Kalevansuo now functions as a significant CO2 sink, a small sink of CH4 and a small source of N2O. According to the flux measurement data it can be concluded that the forest-drainage did not have a positive climate warming feedback impact. A combination of autogenic and allogenic factors such as climate, fires and human disturbance have affected Kalevansuo development. The development was slow lasting for thousands of years, but also rapid, fire-induced changes occurred. This study agrees with the theory that climate change may strengthen the carbon sink feedback effect of boreal bogs, if forest-drainage simulates the effect of a warming climate on northern bogs.
  • Kokko, Sini-Maaria (2013)
    The Cu-Rautuvaara iron-oxide copper gold (IOCG) deposit is located in the western part of the Central Lapland Greenstone belt. Cu-Rautuvaara and several other IOCG deposits are located next or within of the SSW-NNE trending Kolari-Pajala Shear Zone. Deposits are formed in the contacts of the ca. 1860 Ma Haparanda Suites monzonite-diorite intrusions and the >2050 Ma Savukoski Group supracrustal rocks. At Cu-Rautuvaara deposit Cu-Au ore is hosted by magnetite-disseminated albitite. Host rocks for the other deposits in the Kolari area are skarns and ironstones. The wall and the host rocks are hydrothermally altered. Alterations can be roughly divided to proximal and distal zones which are displaying widespread and irregular alteration zones. The distal alteration is characterized by albite ± biotite ± K-feldspar and the proximal alteration albite + magnetite ± phlogopite ± gedrite ± amphibolite ± sulphides ± clinopyroxene. Based on the mass balance calculations Zr, TiO2 and Al2O3 were immobile during the alteration. Calculations indicated that main gains for albitites were Na2O, Fe2O3, Cu and Ni. For diorites and metavolcanites gains were CaO, K2O, Ce and Ba. Albitite protolith determination by its texture and mineral assemblage is unreliable because of the intense hydrothermal alteration. Based on immobile element correlation data suggest that metavolcanites are the most preferential protolith for albitites. The main oxide in the deposits is magnetite, which locally has accessory ilmenite exsolved from it. The main sulphides are chalcopyrite, pyrite and pyrrhotite. Oxides and sulphides element contents were determined by electron microprobe analyses. Based on analyses Au occurs as native Au-Ag grains in chalcopyrite. Major trace element in pyrrhotite is Ni (0.1– 0.8 wt. %). Based on major trace elements there are two types of pyrites with Co (<3 wt. %) and Ni (<3.5 wt. %). Major trace elements in magnetites are Al2O3 (0.01 – 0.71 wt. %), V2O (<0.23 wt. %) and Cr2O3 (<0.27 wt. %). Some magnetites have also MnO (<0.18 wt. %) as trace element. The trace element contents and ore mineral textures suggest that there were two stages of mineralization events for both sulphides and oxides.
  • Lähteenmäki, Tanja (2016)
    Orijärvi mine was the first coppermine in Finland and it's located in Kisko area (Varsinais-Suomi, Salon Seutukunta). Orijärvi mine was operating in years 1757–1956 and during that time sulfide ore (Cu, Pb, Zn) was exploit. Mine was closed without any after treatment done on its operating areas. Studies concerning heavy metal analysis and diatom analysis has been carried out earlier from lake sediments of nearby Lake Orijärvi. Results of these studies reach out up to year 2000. Previous studies testify that acid mine drainage leaching from Orijärvi mine area has affected harmfully to lake Orijärvi during the mining and especially after the closure of the mine. Even though significant environmental impacts of the mine area are demonstrated, there is still no reclamation plan to take care of the mining area. Environmental research of present effect of Orijärvi mine tailing area to lake Orijärvi and to its diatom communities was carried out by diatom analysis from the lake sediment core, by investigating locations of all the mining operations and surveying the loading routes from mine to Lake Orijärvi. Some reclamation options for the tailing area are proposed in this study. In autumn 2014 a lake sediment core was taken from Orijärvi and diatom analysis was carried out to observe diatom taxa representing years 2000–2014. Lake Orijärvi water quality was observed using water quality information from Hertta-database and from previous studies. The functionality of peat covered dam witch partly blocks tailing area was also estimated. Loading routes were detected by using previous studies, stream diatom analysis and watershed modeling. The results reveals that the mining area still affects harmfully lake Orijärvi. Based on the water quality and diatom analysis, biological status of Lake Orijärvi is poor. There are no signs of recovery in diatom communities and heavy metal concentration are high in the lake water. Two loading routes from Orijärvi mine to Lake Orijärvi were identified. One route transports pollution from northern part of the mine and the other route transports pollution from the tailing area to Lake Orijärvi. There was insufficient evidence to properly evaluate functionality of the dams. In situ -cleaning options and passive water treatment options are recommended for reclamation options of the tailing area. Orijärvi mine has a significant environmental effect on nearby areas and Lake Orijärvi and therefore whole mining environment should be restored.
  • Ridaskoski, Timo (2014)
    Gold from orogenic deposits represents one third of the world's total gold production. Most orogenic gold ores contain significant amounts of barren waste rocks that are costly to process. The aim of this work was to evaluate the potential of sensor-based sorting (SBS) of quartz vein hosted orogenic gold ores. Jokisivu is an orogenic gold deposit operated by Dragon Mining Oy. A diorite to gabbro intrusion host the ore body that is located in Häme-belt near to Pirkanmaa belt, which are characterized by metamorphic sedimentary and igneous rocks. The deformed and boudinaged quartz vein ore zone thickness varies from centimeters to few meters and is constrained to a shear zone in WNW-ESE- and WSW-ENE- directions. Variably thick pegmatite veins occur often in close contact within the ore zone. The statistical diamond drill core database evaluation showed a clear correlation between gold and quartz veins. According to the drill cores photos auriferous quartz veins and barren host rocks have sharp visually observable contacts. The quartz rocks are white and diorite waste rocks are black. From the two development ores bulk samples were collected: one 18-ton marginal-grade sample from the Arpola ore body and 29-ton high-grade sample from the Kujankallio ore body. A jaw crusher was used for primary crushing. The bulk samples were crushed and screened, which resulted in an approximately 50/50 coarse to fine particles ratio. Over 1.5 tons of screen overflow (> 30 mm) was sampled for SBS tests. Additionally 900 kg of underflow were collected for a secondary sorting study. The SBS tests were done at Tomra in Germany. PRO (Processing) series chute-type optical sorter was used. It divides a conditioned materials feed to ore and waste rocks by color difference. A rock was sorted waste if its surfaces contained less than two percent white pixels. Similarly five percent sorting threshold was tested. Results showed that 41 – 61 wt% of waste was removed from the marginal-grade Arpola ore with 96 % to 93 % gold recovery. In addition, the gold grade improved from 5.1 ppm to 8.2 – 12.0 ppm. The high-grade Kujankallio ore showed 15 – 31 wt% waste rock removal and 97 to 92 % gold recoveries. The gold grade rose from 7.2 ppm to 8.2 – 9.6 ppm. In addition, the quality of the products improved when harmful minerals such as arsenopyrite and pyrrhotite were reduced. Hand sorting was used for evaluation of the SBS results. Approximately 1.5 tons of sorted rocks were classified according to increasing quartz-vein content and the rock type features. The hand sorting showed that optical sorting is sensitive and adjustable even to subtle materials features. The diorite waste, altered rocks and low-grade quartz rocks were easily separated from the sorting feed material. The gold concentration in the waste rocks was low in the Arpola SBS sample (0.5 – 0.6 ppm) and slightly higher in the Kujankallio sample (0.8 – 1.7 ppm) Economic evaluation of SBS is challenging, because a valid calculation needs to account for the entire production chain from mining to tailings handling. Decreased waste rock dilution (WRD) has the most significant impact on economy as it reduces milling, transportation and tailings costs. More importantly, a significant reduction in mill capacity requirements is achievable by SBS. Numerous positive effects of sorting are significant increment in head grade, homogenous feed, various environmental aspects, decreased chemicals and water usage. The SBS is suitable for marginal- and low-grade orogenic gold ores where sharp and detectable contact between the ore and waste rocks exists. The results indicate that certain low-grade deposits, which were previously considered uneconomic mineralizations, are convertible to ore by SBS. In Brownfield mines, SBS can allow the utilization of the marginal mineral resources more accurately. Greenfield projects may benefit from smaller concentrator sizes and time related savings, which reduce CAPEX costs. The economic benefits are always case dependent.
  • Luostarinen, Tiia (2017)
    The Arctic regions are believed to be most strongly affected by the climate change, with the rapid loss of sea ice during the past decades and amplified polar warming showing a clear signal of recent warming. To understand the future climate change and its mechanisms, past reconstructions of the climate variability are needed. The oceanographic conditions in Kongsfjorden, NW Svalbard, are strongly related to the characteristics of the West Spitsbergen Current (WSC), which transports Atlantic Water (AW) and therefore also heat and salt into the Arctic Ocean. It has previously been shown that changes in the inflow of AW can have a major impact on the environment of the Svalbard area. This study aims to elucidate the fluctuations of AW and to reconstruct the sea surface temperatures in Kongsfjorden during the last 500 years. Marine subfossil diatom assemblages from Kongsfjorden, NW Svalbard, were used to investigate sea surface temperatures (SST) and sea ice variability in high temporal resolution. A 49 cm long marine sediment core was analyzed for diatoms and grain size at 1.0 cm intervals. Diatoms were only abundant in the top 16 cm of the core. The AMS 14C dates suggest that the diatom data represents ca. the last 500 years. The diatom-based SST reconstruction based on the North Atlantic surface sediment sample calibration data set and WAPLS transfer function method indicates temperature variation between 4.1 to 6.0 ˚C with a mean temperature of 4.8 ˚C. The qualitative sea ice reconstruction is based on the Marginal Ice Zone (MIZ) diatom assemblage, and the results are compared with factor analysis results. A cooling trend both in SST and sea ice during the Little Ice Age can be seen throughout the past 500 years with a very recent warming during the past decades. Grain size is dominated by clay and silt, but in the upper 15 cm of the core the coarser sand fraction increases to up to 40 %, indicating change in depositional conditions. The sea ice has been present in the area throughout the past 500 years, and the changes in both SST and MIZ species reflect the changes of the different water masses in the area. A gradual warming of 1.6 °C since LIA is seen, indicating a recent increase in the AW inflow that corresponds to the measured modern temperature of 5.8 ˚C.
  • Virtanen, Ville Juhani (2017)
    Geological Survey of Finland carried out extensive bedrock mapping in the poorly known southeastern part of the Central Finland Granitoid Complex (CFGC) between 2012 and 2016. Majority of the area consists mainly of 1.89–1.88 Ga I-type granitoids that are synkinematic with respect to main collisional event of the Svecofennian orogeny. Crosscutting the synkinematic rocks, a minor suite of 1.88–1.87 Ga A-type granitoids, postdate the main collisional event and are hence referred to as postkinematic. In this Master's thesis, lithological, petrographical, and geochemical features of four postkinematic granitoid intrusions at the Riitalampi, Viininperä, and Korloppinen localities are described. These intrusions are weakly to non-foliated quartz monzonites and granites with biotite and hornblende as the main mafic silicates. Pyroxene-bearing varieties are found in Korloppinen. The geochemistry of the studied intrusions is characterized by high FeO, K2O, Ba, and Zr as well as low MgO, CaO and Sr contents that are characteristic to previously studied postkinematic rocks of the CFGC. U-Pb ages of 1879 ± 4 Ma for Riitalampi and 1882 ± 3 Ma for Viininperä intrusions confirm that these intrusions are coeval with the previously studied postkinematic intrusions. Whole-rock geochemical composition of Riitalampi, Viininperä, and Korloppinen intrusions is similar to that of well studied A-type granites, which formed by partial melting of mantle-derived basaltic source rocks. However, Riitalampi and Viininperä intrusions have certain geochemical deviation from typical A-type geochemistry e.g. high Al2O3, Ba, and Eu contents as well as volcanic arc granite (VAG) affinity of some of the samples. These geochemical features suggest that the partial melts from the mantle-derived basaltic source mixed with partial melts derived from deep crustal source. Field observations of mafic microgranular enclaves (MME) indicate that coeval mafic-felsic magmatism is related to the formation of the Riitalampi and Viininperä intrusions. Synplutonic dyke and ubiquitous MME observed in the Riitalampi intrusion point to continuous mafic input during crystallization of the intrusion. Petrographic observations combined with geochemical modeling suggest mingling and chemical exchange, but not mixing, between the magmas in Riitalampi. The coeval mafic-felsic magmatism in the Viininperä intrusion was spatially and temporally more restricted, and took place only during the formation of the syenogranitic northern margin.
  • Lepistö, Tiina (2014)
    The soft soil sediments in Southern Finland were originally deposited during different stages of the Baltic Sea. There are many problems concerning construction on these soft soils. These include, among others, sinking and stability problems. Demands for construction work on soft soil areas are growing all the time and it is therefore important to study the geological and geophysical properties of the soil. This thesis examines the possibility of drawing conclusions on soft soil stratigraphy with the help of in situ measurements. In situ measurements are performed on-site and they speed up working because separate sampling and laboratory analysis are not required. Measurements were carried out in the Helsinki Metropolitan Area. Sediment depositions' apparent resistivity, temperature and magnetic susceptibility were measured with probes installed on the tip of bog drills. The results were compared to an existing stratigraphic data and other information. Research also included method testing with susceptibility measuring instrument purchased by Geological Survey of Finland. In situ measurements of apparent resistivity provides reliable information on soft soil stratigraphy. Resistivity profiles can be used to distinguish topsoil and different clays. In addition, sandy intermediate layers are well distinguished in these high resolution measurements. The apparent resistivity varies similarly in every research area. In situ measurements of magnetic susceptibility can be used to estimate the incidence of sulphide clays. In this work no conclusions could be drawn regarding the variability of susceptibility due to the weaknesses of the apparatus. Use of the apparatus revealed several problems. The most notable is the lack of a temperature sensor.
  • Romu, Ilona (2013)
    Jurassic (159 Ma), ultrapotassic, mica-rich dykes of Kjakebeinet represent the youngest magmatic rock type observed in western Dronning Maud Land, Antarctica; abundant xenoliths are enclosed by the dykes. A petrographical description of the xenoliths and one of the dykes was made to distinguish the rock types and to gain information of the unknown basement below Kjakebeinet, situated on the southern edge of Vestfjella mountainrange. The mineral chemistry and petrography of the xenoliths and one of the lamproite dykes were studied using petrographic microscope and electron microprobe (EDS-mode). Rb-Sr and Sm-Nd isotopic determinations were made on metagabbroic and carbonatite xenoliths. Most of the xenoliths record evidence of granulite facies metamorphosis and they represent several crustal rock types. Tonalite, alkali feldspar granite, and augen gneisses, metagabbros and metasedimentary xenoliths were observed. Two of the xenoliths, carbonatite, and phlogopite rock, are cognate. This thesis shows that the crust below the southern Vestfjella is heterogenic, and contains differentiated metaigneous rock types. The xenoliths include Proterozoic basement gneisses, and possibly also Permian sedimentary rocks and Mesozoic igneous rocks. The studied lamproite dyke is phlogopite-sanidinediopside-olivine lamproite which shows affinity to madupitic lamproites and group II kimberlites.
  • Mäkimattila, Otso (2015)
    The Ponostama ultramafic intrusion, located within the Central Lapland Greenstone Belt, comprises of pyroxenitic, olivine pyroxenitic and peridotitic units that were emplaced stratiformally between Sodankylä Group tuffs and epiclastics. The intrusion, previously unknown on geological maps, is located in an area of known magmatic sulfide deposits and is Ni-depleted, which indicates prospectivity. Petrographic, geochemical and thermodynamic methods were used to geologically describe the intrusion. In addition Kevitsa Ni-Cu deposit and seven other un-mineralized ultramafic occurrences from CLGB were used as a reference group to compile a mineralogical and trace element comparison and to evaluate ore potential. Cumulate texture is abundant in Ponostoma and a common silicate mineral assemblage consists of tremolite, serpentine, chlorite and variable amounts of primary or metamorphic olivine. Amhibolite facies recrystallization has locally produced poikiloblastic olivine porhphyroblasts. Pseudosection indicates a minimum temperature of 450 °C and low H2O activity for metamorphic olivine growth. Major element compositions have little variation within lithological units and Mg# varies between 70 and 80. Olivine compositions vary between Fo60 and Fo70, which indicates relatively evolved parent magma composition. Metamorphic olivines are less magnesian than primary olivines, but no other compositional differences occur. The Ni and Cu concentrations are similar to un-mineralized host rocks of the Kevitsa deposit due to formation of a sulfide liquid. Immobile trace element concentrations are close to values of the 2.2 Ga Taljavaara intrusion. Low sulfide content together with low Ni and Fo in olivine indicate low ore potential.
  • Alatarvas, Raisa (2017)
    The Landsort Deep is the deepest part of the Baltic Sea. It is located just south from the postulated margins of the early Weichselian glacial, and the deep displays a high-resolution sediment sequence from late Weichselian and Holocene. The physical properties and characterisation of late and postglacial sediments from the Landsort Deep enabled the interpretation of the sediment responses to late Weichselian and Holocene glacial settings. The sediment stratigraphy of the Landsort Deep reflects variations of salinity in the Baltic Sea Basin, and it enables the identification of four major stages in the history of the Baltic Sea: Baltic Ice Lake, Yoldia Sea, Ancylus Lake and Littorina Sea. The samples studied are from cores from Hole M0063C. The cores were recovered during the Integrated Ocean Drilling Program (IODP) Expedition 347, “Baltic Sea Paleoenvironment”. Site M0063 is divided into seven lithostratigraphic units, and the samples are from Unit VI (54–93 ambsf) and Unit V (48–54 ambsf). Sediment analyses and the interpretation of the sedimentary environment of Units VI and V are based on grain-size analysis by laser diffractometry, loss on ignition (LOI) determination, and on the IODP Expedition 347 physical properties dataset. The uniquely long varved glacial clay sequence of Units VI and V gives indications of the Scandinavian Ice Sheet and the sedimentation of the Baltic Sea Basin responded to climate fluctuations. The lowermost part of the thick sediment column comprising Units VI and V, displays ice-proximal settings, and the upper part represents ice-distal settings. The correlation of the sedimentary features to well-known geological events in the Baltic Sea region enabled the relative age determination of the Units VI and V. The sediments are deposited during the Baltic Ice Lake stage and the transition into the Yoldia Sea stage, roughly estimated between 13.5 and 11.5 ka. Comparison to different late and postglacial settings e.g. marine and terrestrial, illustrated conformities in various glacial sedimentary settings.